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Ethylene Ethene C2H4 Properties

Reference data and engineering information about ethylene ethene c2h4 properties for miscellaneous applications.

ethyleneetheneC2H4propertiesData Table

Overview

Engineering reference data for Ethylene Ethene C2H4 Properties in miscellaneous.

Key Formulas

Unit Conversion

y=xky = x \cdot k

Multiply by conversion factor.

Linear Interpolation

y=y1+(xx1)(y2y1)x2x1y = y_1 + \frac{(x - x_1)(y_2 - y_1)}{x_2 - x_1}

Estimate between two known points.

Percentage

p=partwhole×100%p = \frac{\text{part}}{\text{whole}} \times 100\%

Part as fraction of whole.

Variables

SymbolDescriptionUnit
xxInput value
yyOutput value
kkConversion factor

Thermophysical Properties Data

The following table contains key thermophysical and chemical properties of ethylene gas at 25 °C (298 K) and 1 bara unless otherwise specified.

38 rows
Thermophysical and chemical properties of ethylene (C₂H₄). Values are for gas phase at 25 °C and 1 bara unless noted otherwise.
Property
Value (SI)
Unit
Value (Imperial)
Unit
Autoignition temperature723K450°C
Boiling Point169K-104°C
Critical density7.63mol/dm³214kg/m³
Critical pressure5.06MPa50.6bar
Critical temperature282.4K9.2°C
Critical volume131cm³/mol0.00467m³/kg
Density (gas)40.6mol/m³1.138kg/m³
Density (liquid, -104°C)20567mol/m³577kg/m³
Flammable (gas & liquid)yes, highly
Flash point137K-136°C
Gas constant (individual, R)296.4J/(kg·K)0.0823Wh/(kg·K)
Gibbs free energy of formation (gas)68kJ/mol1042Btu/lb
Heat of combustion (gas)-1411kJ/mol-21626Btu/lb
Heat of formation (gas)52.4kJ/mol803Btu/lb
Heat of evaporation (-104°C)13.6kJ/mol207.7Btu/lb
Heat capacity, Cp (gas)42.9J/(mol·K)1.53kJ/(kg·K)
Heat capacity, Cp (liquid, -104°C)67.4J/(mol·K)2.40kJ/(kg·K)
Heat capacity, Cv (gas)34.6J/(mol·K)1.24kJ/(kg·K)
Heat capacity, Cv (liquid, -104°C)38.7J/(mol·K)1.38kJ/(kg·K)
Ionization potential10.5eV
log KOW1.13
Melting point104.15K-169.0°C
Molecular Weight28.054g/mol0.06185lb/mol
Solubility in water (25°C)0.131mg/ml
Sound velocity330m/s1082ft/s
Specific Gravity (gas)0.978(relative to air)
Specific Heat Ratio (gas), Cp/Cv1.24
Specific Heat Ratio (liquid), Cp/Cv1.74
Specific Volume0.0247m³/mol0.879m³/kg
Standard molar entropy, S° (gas)219.32J/(mol·K)1.87Btu/(lb·°F)
Standard molar entropy, S° (liquid)117.8J/(mol·K)1.00Btu/(lb·°F)
Surface tension (-104°C)16.00dynes/cm0.016N/m
Thermal Conductivity0.020W/(m·°C)0.0118Btu/(hr·ft·°F)
Triple point pressure0.000122MPa0.0177psi
Triple point temperature104.0K-169.16°C
Vapor (saturation) pressure6.9449MPa1007.30psi
Viscosity, dynamic (absolute)0.0103cP
Viscosity, kinematic9.05cSt

Source: engineeringtoolbox.com

Phase Behavior and Critical Points

Ethylene is a gas under standard conditions. Its phase state changes with pressure and temperature, as shown on its phase diagram.

  • Critical Point: This is the point on the phase diagram where the distinction between the liquid and gas phases disappears. For ethylene, this occurs at 282.4 K (9.2 °C) and 5.06 MPa. At or above this temperature and pressure, ethylene exists as a supercritical fluid.
  • Triple Point: This is the unique temperature and pressure where the solid, liquid, and gas phases coexist in equilibrium. For ethylene, the triple point is at 104.0 K (-169.16 °C) and 0.000122 MPa.
  • Saturation Curve: The curve between the triple point and the critical point represents the ethylene boiling point as a function of pressure (or equivalently, the saturation pressure as a function of temperature).

Detailed data for ethylene's properties as a function of temperature and pressure can be found for:

  • Density and specific weight
  • Dynamic and kinematic viscosity
  • Specific heat (Cp and Cv)
  • Thermal conductivity

Key Thermodynamic Relationships

The Specific Heat Ratio (γ\gamma or kk) is a fundamental property for process engineering, especially for compressible flow and compression calculations. γ=CpCv\gamma = \frac{C_p}{C_v} For ethylene gas, γ=1.24\gamma = 1.24.

The individual gas constant (RspecR_{spec}) can be calculated from the universal gas constant (R=8.314J/(mol⋅K)R = 8.314 \, \text{J/(mol·K)}) and the molar mass (M=28.054g/molM = 28.054 \, \text{g/mol}): Rspec=RMR_{spec} = \frac{R}{M} This yields the value of 296.4J/(kg⋅K)296.4 \, \text{J/(kg·K)} listed in the properties table.

References