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Heat Work Energy

Reference data and engineering information about heat work energy for thermodynamics applications.

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Overview

Engineering reference data for Heat Work Energy in thermodynamics.

Key Formulas

First Law

ΔU=QW\Delta U = Q - W

Energy is conserved — heat added minus work done.

Ideal Gas Law

PV=nRTPV = nRT

Relates pressure, volume, and temperature of an ideal gas.

Heat Transfer

Q=mcΔTQ = mc\Delta T

Sensible heat transfer.

Carnot Efficiency

η=1TC/TH\eta = 1 - T_C/T_H

Maximum efficiency between two temperatures.

Variables

SymbolDescriptionUnit
UUInternal energyJ
QQHeatJ
WWWorkJ
PPPressurePa
VVVolume
TTTemperatureK

Enthalpy and Heat Capacity

Specific enthalpy represents the total energy per unit mass of a substance, accounting for both its internal energy and the energy from applied pressure. It is commonly measured in J/kg or kJ/kg.

Heat capacity defines the total heat energy required to raise the temperature of an entire system by one degree.

Specific Heat Capacity

Specific heat capacity (cc) is the heat required to raise the temperature of a unit mass of a substance by one degree. Its value depends on whether the heating process occurs at constant pressure (cpc_p) or constant volume (cvc_v).

  • For solids and liquids, the volume change with temperature is negligible, so cpcvc_p \approx c_v.
  • Water has a high specific heat capacity (4.19 kJ/kgK\approx 4.19 \text{ kJ/kg} \cdot \text{K}), making it an effective heat transfer fluid.

Unit Conversions for Heat

Key energy unit equivalencies: 1 cal=4.184 J1 \text{ cal} = 4.184 \text{ J} 1 J=1 Ws=2.78×104 Wh=2.78×107 kWh1 \text{ J} = 1 \text{ Ws} = 2.78 \times 10^{-4} \text{ Wh} = 2.78 \times 10^{-7} \text{ kWh}

Heat Transfer and Work Examples

Calculating Heat for Temperature Change

The heat (QQ) required to change the temperature of a mass is given by: Q=cpmΔTQ = c_p \cdot m \cdot \Delta T

Example: Heating 1.0 kg of water from 0C0^\circ\text{C} to 100C100^\circ\text{C}: Q=(4.19 kJ/kgK)×(1.0 kg)×(100 K)=419 kJQ = (4.19 \text{ kJ/kg} \cdot \text{K}) \times (1.0 \text{ kg}) \times (100 \text{ K}) = 419 \text{ kJ}

Calculating Mechanical Work

Work (WW) is the product of a force and the distance moved in the direction of the force: W=FlW = F \cdot l

Example: The work done by a 100 N100 \text{ N} force moving an object 50 m50 \text{ m}: W=(100 N)×(50 m)=5000 JW = (100 \text{ N}) \times (50 \text{ m}) = 5000 \text{ J}

Work Against Gravity

The work done in lifting a mass is given by: W=mghW = m \cdot g \cdot h

Example: Lifting a 100 kg100 \text{ kg} mass by 10 m10 \text{ m}: W=(100 kg)×(9.81 m/s2)×(10 m)=9810 JW = (100 \text{ kg}) \times (9.81 \text{ m/s}^2) \times (10 \text{ m}) = 9810 \text{ J}

References