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Lead Acid Battery

Reference data and engineering information about lead acid battery for material properties applications.

leadacidbattery

Overview

Engineering reference data for Lead Acid Battery in material science and properties.

Key Formulas

Stress

σ=FA\sigma = \frac{F}{A}

Force per unit area.

Strain

ε=ΔLL0\varepsilon = \frac{\Delta L}{L_0}

Change in length per original length.

Hooke's Law

σ=Eε\sigma = E \varepsilon

Stress proportional to strain in elastic region.

Thermal Expansion

ΔL=αL0ΔT\Delta L = \alpha L_0 \Delta T

Length change due to temperature.

Variables

SymbolDescriptionUnit
σ\sigmaStressPa
ε\varepsilonStrain
EEYoung's modulusPa
α\alphaThermal expansion coefficient1/°C
ΔT\Delta TTemperature change°C

State of Charge Indicators

Understanding the relationship between specific gravity and state of charge (SOC) is essential for lead-acid battery maintenance:

ConditionSpecific Gravity Range
OverchargedAbove 1.300
Fully Charged~1.265
Normal Operation1.200 - 1.265
Very Low Capacity1.130 - 1.150
DischargedBelow 1.120

Temperature Effects on Battery Performance

Lead-acid battery performance is significantly affected by temperature:

  • Efficiency: Battery efficiency decreases as temperature drops, with optimal performance typically around 25°C (77°F)
  • Specific Gravity: The specific gravity reading in a fully charged battery varies with temperature and must be temperature-compensated for accurate readings

Specific Gravity Temperature Compensation

The specific gravity of a fully charged lead-acid battery varies with electrolyte temperature. Standard specific gravity values (typically 1.265 at 25°C) should be adjusted:

SGcorrected=SGmeasured+0.0007×(TreferenceTmeasured)SG_{corrected} = SG_{measured} + 0.0007 \times (T_{reference} - T_{measured})

Where:

  • SGcorrectedSG_{corrected} = temperature-compensated specific gravity
  • SGmeasuredSG_{measured} = specific gravity reading at measured temperature
  • TreferenceT_{reference} = reference temperature (typically 25°C or 77°F)
  • TmeasuredT_{measured} = actual electrolyte temperature

This compensation is critical because specific gravity readings taken at temperatures significantly different from 25°C can be misleading when assessing state of charge.

References