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Naming Rule Covalent Ionic Binary Compound Salt

Reference data and engineering information about naming rule covalent ionic binary compound salt for chemistry applications.

namingrulecovalentionic

Overview

Engineering reference data for Naming Rule Covalent Ionic Binary Compound Salt in chemistry.

Key Formulas

Ideal Gas Law

PV=nRTPV = nRT

Pressure × Volume = moles × gas constant × temperature.

Molarity

M=nVM = \frac{n}{V}

Moles of solute per liter of solution.

pH

pH=log10[H+]pH = -\log_{10}[H^+]

Measure of acidity.

Variables

SymbolDescriptionUnit
PPPressurePa
VVVolume
nnMolesmol
RRGas constant8.314 J/(mol·K)

Naming Rules for Binary Compounds

Ionic Compounds

Binary ionic compounds contain a positive ion (cation) and a negative ion (anion). The cation is typically a metal and is always written first in both the formula and the name.

Basic Rules:

  • The cation is always named first and the anion second
  • A cation takes its name from the name of the element (e.g., K⁺ → potassium)
  • An anion is named by taking the first part of the element name and adding -ide (e.g., Br⁻ → bromide)

Oxyanion Naming Conventions

For oxyanion series (polyatomic ions with varying numbers of oxygen atoms):

Series LengthNaming Pattern
Two membersSmaller O count → -ite, Larger O count → -ate
More than twoFewest O → hypo-...-ite, Most O → per-...-ate

Monatomic Ions Reference

14 rows
Common monatomic cations and anions with their names
Cation
Cation Name
Anion
Anion Name
Al³⁺AluminiumBr⁻Bromide
Ba²⁺BariumCl⁻Chloride
Be²⁺BerylliumF⁻Fluoride
Ca²⁺CalciumH⁻Hydride
Cs⁺CesiumI⁻Iodide
H⁺HydrogenN³⁻Nitride
Li⁺LithiumO²⁻Oxide
Mg²⁺MagnesiumP³⁻Phosphide
K⁺PotassiumS²⁻Sulfide
Rb⁺Rubidium
Ag⁺Silver
Na⁺Sodium
Sr²⁺Strontium
Zn²⁺Zinc

Source: engineeringtoolbox.com

Polyatomic Ions Reference

11 rows
Common polyatomic ions and their names
Ion
Name
Ion
Name
NH₄⁺AmmoniumMnO₄⁻Permanganate
C₂H₃O₂⁻AcetateNO₂⁻Nitrite
CO₃²⁻CarbonateNO₃⁻Nitrate
HCO₃⁻Hydrogen carbonateOH⁻Hydroxide
ClO⁻HypochloriteO₂²⁻Peroxide
ClO₂⁻ChloritePO₄³⁻Phosphate
ClO₃⁻ChlorateHPO₄²⁻Hydrogen phosphate
ClO₄⁻PerchlorateH₂PO₄⁻Dihydrogen phosphate
CN⁻CyanideSO₃²⁻Sulfite
CrO₄²⁻ChromateSO₄²⁻Sulfate
Cr₂O₇²⁻DichromateHSO₄⁻Hydrogen sulfate

Source: engineeringtoolbox.com

Type I Binary Ionic Compounds

Type I compounds contain a metal that forms only one type of cation (e.g., Na⁺, Ca²⁺).

7 rows
Examples of Type I binary ionic compound naming
Compound
Ions Present
Name
CaSCa²⁺, S²⁻Calcium sulfide
CsBrCs⁺, Br⁻Cesium bromide
Li₃NLi⁺, N³⁻Lithium nitride
MgOMg²⁺, O²⁻Magnesium oxide
KFK⁺, F⁻Potassium fluoride
AgIAg⁺, I⁻Silver iodide
NaClNa⁺, Cl⁻Sodium chloride

Source: engineeringtoolbox.com

Type II Binary Ionic Compounds

Type II compounds contain metals that can form more than one type of cation. The charge is specified using Roman numerals in parentheses.

12 rows
Type II cations with systematic and alternate naming conventions
Ion
Systematic Name
Alternate Name
Co²⁺Cobalt(II)Cobaltous
Co³⁺Cobalt(III)Cobaltic
Cu⁺Copper(I)Cuprous
Cu²⁺Copper(II)Cupric
Fe²⁺Iron(II)Ferrous
Fe³⁺Iron(III)Ferric
Pb²⁺Lead(II)Plumbous
Pb⁴⁺Lead(IV)Plumbic
Hg₂²⁺Mercury(I)Mercurous
Hg²⁺Mercury(II)Mercuric
Sn²⁺Tin(II)Stannous
Sn⁴⁺Tin(IV)Stannic

Source: engineeringtoolbox.com

Binary Covalent Compounds

Covalent compounds contain two nonmetals. Naming follows these rules:

  • First element uses the full name
  • Second element is named as an anion (with -ide suffix)
  • Prefixes indicate atom count: mono- (1), di- (2), tri- (3), tetra- (4), penta- (5), hexa- (6), hepta- (7), octa- (8)
  • The prefix mono- is never used for the first element
  • When oxygen follows a vowel-ending prefix, the vowel is dropped (e.g., monoxide, tetroxide, pentoxide)
6 rows
Examples of covalent compound naming (nitrogen oxides)
Compound
Systematic Name
Common Name
NONitrogen monoxideNitric oxide
NO₂Nitrogen dioxide
N₂ODinitrogen monoxideNitrous oxide
N₂O₃Dinitrogen trioxide
N₂O₄Dinitrogen tetroxide
N₂O₅Dinitrogen pentoxide

Source: engineeringtoolbox.com

Interactive Charts

Common monatomic cations and anions with their names

Common polyatomic ions and their names

Examples of Type I binary ionic compound naming

Type II cations with systematic and alternate naming conventions

Examples of covalent compound naming (nitrogen oxides)

References