Skip to main content
Speclore

Stoichiometric Combustion

Reference data and engineering information about stoichiometric combustion for combustion applications.

stoichiometriccombustion

Overview

Engineering reference data for Stoichiometric Combustion in combustion engineering.

Key Formulas

Heat Release

Q=m˙HVQ = \dot{m} \cdot HV

Fuel energy release rate.

Air-Fuel Ratio

AF=mairmfuelAF = \frac{m_{air}}{m_{fuel}}

Mass of air per mass of fuel.

Excess Air

EA=O221O2×100%EA = \frac{O_2}{21 - O_2} \times 100\%

From flue gas oxygen measurement.

Variables

SymbolDescriptionUnit
QQHeat release rateW
m˙\dot{m}Mass flow ratekg/s
HVHVHeating valueJ/kg
AFAFAir-fuel ratio

Combustion with Excess Air

The chemical equation for methane burned with 25% excess air is:

CH4+1.25×2(O2+3.76N2)CO2+2H2O+0.5O2+9.4N2CH_4 + 1.25 \times 2(O_2 + 3.76 N_2) \rightarrow CO_2 + 2 H_2O + 0.5 O_2 + 9.4 N_2

The following table provides approximate values for CO₂ and O₂ in the flue gas as a function of excess air for various fuels.

6 rows
Approximate CO₂ and O₂ concentrations in flue gas as a function of excess air for various fuels.
Excess Air(%)
Natural Gas(% vol CO₂)
Propane/Butane(% vol CO₂)
Fuel Oil(% vol CO₂)
Bituminous Coal(% vol CO₂)
Anthracite Coal(% vol CO₂)
O₂ in Flue Gas(% vol)
0121415.518200
2010.51213.515.516.53
409101213.5145
6089101212.57.5
807891111.59
1006689.51010

Source: engineeringtoolbox.com

Interactive Charts

Methane (CH₄): Thermophysical Properties and Phase Diagram

References