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Thermodynamics

Reference data and engineering information about thermodynamics for miscellaneous applications.

thermodynamics

Overview

Engineering reference data for Thermodynamics in miscellaneous.

Key Formulas

Unit Conversion

y=xky = x \cdot k

Multiply by conversion factor.

Linear Interpolation

y=y1+(xx1)(y2y1)x2x1y = y_1 + \frac{(x - x_1)(y_2 - y_1)}{x_2 - x_1}

Estimate between two known points.

Percentage

p=partwhole×100%p = \frac{\text{part}}{\text{whole}} \times 100\%

Part as fraction of whole.

Variables

SymbolDescriptionUnit
xxInput value
yyOutput value
kkConversion factor

Common Thermodynamic Formulas

Several fundamental formulas are essential for engineering calculations beyond the core laws:

Ideal Gas Law: PV=nRTPV = nRT Where P is pressure, V is volume, n is the amount of substance, R is the universal gas constant, and T is absolute temperature.

Fourier's Law of Heat Conduction: Q˙=kAdTdx\dot{Q} = -kA \frac{dT}{dx} Where Q˙\dot{Q} is the heat transfer rate, kk is the thermal conductivity, AA is the cross-sectional area, and dT/dxdT/dx is the temperature gradient.

Carnot Efficiency (theoretical maximum for a heat engine): ηCarnot=1TCTH\eta_{\text{Carnot}} = 1 - \frac{T_C}{T_H} Where THT_H and TCT_C are the absolute temperatures of the hot and cold reservoirs, respectively.

Key Definitions

1st Law of Thermodynamics (Conservation of Energy): Energy cannot be created or destroyed, only converted from one form to another. This implies the total energy of an isolated system is constant.

2nd Law of Thermodynamics: Introduces the concept of entropy (SS). For any spontaneous process, the total entropy of the universe increases. This law governs the direction of processes and sets limits on the efficiency of energy conversion.

Emissivity (ϵ\epsilon): A material's ability to emit absorbed energy as thermal radiation, compared to a perfect black body (ϵ=1\epsilon = 1). It is a dimensionless factor between 0 and 1.

Material Properties Reference

The following table summarizes property ranges for commonly referenced fluids from the source data.

5 rows
Selected thermophysical properties of common materials from engineering reference data.
Material
Property
Value Range
Units
Conditions
AmmoniaDynamic Viscosity (gas/liquid)Consult specific tablesPa·s or cP-73 to 425 °C, 1 to 1000 bara
AmmoniaSpecific Heat (Cp, Cv)Consult specific tablesJ/kg·K or BTU/lb·°F-73 to 425 °C, 1 to 100 bara
AirDensity, Viscosity, Thermal Conductivity, etc.VariableSI & ImperialAt varying temperatures & pressures
ArgonDensity & Specific WeightVariablekg/m³ or lb/ft³At varying temperature & pressure
AluminumRadiation Emissivity0.02 - 0.9 (approx.)DimensionlessUnoxidized, oxidized, or polished

Source: engineeringtoolbox.com

References