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Water Vapor

Reference data and engineering information about water vapor for air psychrometrics applications.

watervapor

Overview

Engineering reference data for Water Vapor in air psychrometrics.

Key Formulas

Humidity Ratio

ω=0.622PvPa\omega = 0.622 \frac{P_v}{P_a}

Mass of water vapor per mass of dry air.

Relative Humidity

ϕ=PvPvs×100%\phi = \frac{P_v}{P_{vs}} \times 100\%

Ratio of actual to saturation vapor pressure.

Wet Bulb Temperature

Twb=TdbPvsPvγT_{wb} = T_{db} - \frac{P_{vs} - P_v}{\gamma}

Temperature measured by wet-bulb thermometer.

Enthalpy of Moist Air

h=cpT+ωhgh = c_p T + \omega h_g

Sensible + latent heat per unit mass of dry air.

Variables

SymbolDescriptionUnit
ω\omegaHumidity ratiokg/kg
ϕ\phiRelative humidity%
PvP_vVapor pressurePa
PvsP_{vs}Saturation vapor pressurePa
TdbT_{db}Dry bulb temperature°C
TwbT_{wb}Wet bulb temperature°C

Water Vapor Specific Heat Data

52 rows
Specific Heat (cp) of Water Vapor (H₂O) vs. Temperature at constant pressure (undissociated states)
Temperature(K)
Specific Heat(kJ/kgK)
1751.85
2001.851
2251.852
2501.855
2751.859
3001.864
3251.871
3501.88
3751.89
4001.901
4501.926
5001.954
5501.984
6002.015
6502.047
7002.08
7502.113
8002.147
8502.182
9002.217
9502.252
10002.288
10502.323
11002.358
11502.392
12002.425
12502.458
13002.49
13502.521
14002.552
15002.609
16002.662
17002.711
18002.756
19002.798
20002.836
21002.872
22002.904
23002.934
24002.962
25002.987
26003.011
27003.033
28003.053
29003.072
30003.09
35003.163
40003.217
45003.258
50003.292
55003.322
60003.35

Source: engineeringtoolbox.com

Important Notes

  • Isobaric (Cₚ) vs. Isochoric (Cᵥ): The data provided is for isobaric specific heat (Cₚ), applicable to systems at constant pressure. Isochoric specific heat (Cᵥ) is used for constant-volume closed systems.
  • Temperature Dependence: Specific heat varies significantly with temperature, increasing approximately 80% from 175 K to 6000 K.
  • High-Temperature Behavior: At temperatures above 1500 K, dissociation of water vapor becomes appreciable, making pressure a significant variable. The provided values assume undissociated states.
  • Engineering Applications: For accurate mass and volume flow calculations in heated or cooled systems, specific heat values should be corrected according to the temperature using this table.

Interactive Charts

Butane - Specific Heat vs. Temperature and Pressure

References