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Loi thermodynamics

Reference data et engineering information about loi thermodynamics pour thermodynamics applications.

lawthermodynamics

Overview

The laws of thermodynamics are fundamental principles governing energy, heat, and work in physical systems.

Key Formulas

Zeroth Law

TA=TB and TB=TCTA=TCT_A = T_B \text{ and } T_B = T_C \Rightarrow T_A = T_C

If two systems are each in thermal equilibrium with a third, they are in equilibrium with each other.

First Law

ΔU=QW\Delta U = Q - W

Change in internal energy = heat added − work done by the system.

Second Law (Clausius)

ΔSQT\Delta S \geq \frac{Q}{T}

Entropy of an isolated system never decreases.

Third Law

limT0S=0\lim_{T \to 0} S = 0

Entropy approaches zero as temperature approaches absolute zero (perfect crystal).

Variables

SymbolDescriptionUnit
UUInternal energyJ
QQHeat added to systemJ
WWWork done by systemJ
SSEntropyJ/K
TTAbsolute temperatureK

References